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天然气水合物;开采技术;降压;固态流化;联合方法 1

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Self-sustained catalytic combustion of CO enhanced by micro fluidized bed: stability operation, fluidization

《环境科学与工程前沿(英文)》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1709-x

摘要:

● Catalytic combustion in fluidized bed realizes efficient heat and mass transfer.

关键词: Self-sustained catalytic combustion     Carbon monoxide     Cu1–xCexOy     Fluidized bed     Computational fluid dynamics    

Development of a hydrodynamic model and the corresponding virtual software for dual-loop circulating fluidized beds

Shanwei Hu, Xinhua Liu

《化学科学与工程前沿(英文)》 2021年 第15卷 第3期   页码 579-590 doi: 10.1007/s11705-020-1953-6

摘要: Dual-loop circulating fluidized bed (CFB) reactors have been widely applied in industry because of their good heat and mass transfer characteristics and continuous handling ability. However, the design of such reactors is notoriously difficult owing to the poor understanding of the underlying mechanisms, meaning it has been heavily based on empiricism and stepwise experiments. Modeling the gas-solid CFB system requires a quantitative description of the multiscale heterogeneity in the sub-reactors and the strong coupling between them. This article proposed a general method for modeling multi-loop CFB systems by utilizing the energy minimization multiscale (EMMS) principle. A full-loop modeling scheme was implemented by using the EMMS model and/or its extension models to compute the hydrodynamic parameters of the sub-reactors, to achieve the mass conservation and pressure balance in each circulation loop. Based on the modularization strategy, corresponding interactive simulation software was further developed to facilitate the flexible creation and fast modeling of a customized multi-loop CFB reactor. This research can be expected to provide quantitative references for the design and scale-up of gas-solid CFB reactors and lay a solid foundation for the realization of virtual process engineering.

关键词: multi-loop circulating fluidized bed     mathematical modeling     energy minimization multiscale     virtual fluidization     mesoscale structure    

Performance of inverse fluidized bed bioreactor in treating starch wastewater

M. RAJASIMMAN, C. KARTHIKEYAN

《化学科学与工程前沿(英文)》 2009年 第3卷 第3期   页码 235-239 doi: 10.1007/s11705-009-0020-0

摘要: Aerobic digestion of starch industry wastewater was carried out in an inverse fluidized bed bioreactor using low-density (870 kg/m ) polypropylene particles. Experiments were carried out at different initial substrate concentrations of 2250, 4475, 6730, and 8910 mg COD/L and for various hydraulic retention times (HRT) of 40, 32, 24, 16, and 8 h. Degradation of organic matter was studied at different organic loading rates (OLR) by varying the HRT and the initial substrate concentration. From the results it was observed that the maximum COD removal of 95.6% occurred at an OLR of 1.35 kg COD/(m ·d) and the minimum of 51.8% at an OLR of 26.73 kg COD/(m ·d). The properties of biomass accumulation on the surface of particles were also studied. It was observed that constant biomass loading was achieved over the entire period of operation.

关键词: inverse fluidization     low-density particles     polypropylene     starch     biofilm    

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-based CO2 capture sorbents

《化学科学与工程前沿(英文)》 2022年 第16卷 第10期   页码 1460-1475 doi: 10.1007/s11705-022-2159-x

摘要: Carbon nanotubes-based materials have been identified as promising sorbents for efficient CO2 capture in fluidized beds, suffering from insufficient contact with CO2 for the high-level CO2 capture capacity. This study focuses on promoting the fluidizability of hard-to-fluidize pure and synthesized silica-coated amine-functionalized carbon nanotubes. The novel synthesized sorbent presents a superior sorption capacity of about 25 times higher than pure carbon nanotubes during 5 consecutive adsorption/regeneration cycles. The low-cost fluidizable-SiO2 nanoparticles are used as assistant material to improve the fluidity of carbon nanotubes-based sorbents. Results reveal that a minimum amount of 7.5 and 5 wt% SiO2 nanoparticles are required to achieve an agglomerate particulate fluidization behavior for pure and synthesized carbon nanotubes, respectively. Pure carbon nanotubes + 7.5 wt% SiO2 and synthesized carbon nanotubes + 5 wt% SiO2 indicates an agglomerate particulate fluidization characteristic, including the high-level bed expansion ratio, low minimum fluidization velocity (1.5 and 1.6 cm·s–1), high Richardson−Zakin index (5.2 and 5.3 > 5), and low Π value (83.2 and 84.8 < 100, respectively). Chemical modification of carbon nanotubes causes not only enhanced CO 2 uptake capacity but also decreases the required amount of silica additive to reach a homogeneous fluidization behavior for synthesized carbon nanotubes sorbent.

关键词: CO2 capture     CNT-based sorbents     fluidization     SiO2 nanoparticles     fluidized bed reactors    

CFD simulation of jet behaviors in a binary gas-solid fluidized bed: comparisons with experiments

Pei PEI, Guiying WU, Bangting YU, Kai ZHANG, Jianchun JIANG, Dongsheng WEN,

《化学科学与工程前沿(英文)》 2010年 第4卷 第3期   页码 242-249 doi: 10.1007/s11705-009-0277-3

摘要: Based on the experimental observation of the fluidization characteristics of solid mixtures (resin and rapeseed) with different densities and sizes, the jet behaviours of the binary system are simulated in a two-dimensional jetting fluidized bed 0.30 m in width and 2.00 m in height. A simple mathematical model, by introducing two additional force terms in both gas and particle phase momentum equations of Gidaspow’s inviscid two-fluid model, is used to explore the effects of jet gas velocity and mixture combination on the jet penetration depth in the fluidized bed with a binary system. Experimental results show that there is a fluidization velocity interval (-) for the resin-on-rapeseed (flotsam-on-jetsam) segregated bed. The simulated jet penetration depth increases with the increase of jet gas velocity and the volume fraction of the flotsam (resin), which is in fair agreement with experimental data. The above findings show that the hydrodynamic model of Brandani and Zhang (2006), by introducing the average physical properties from Goossens et al.(1971), can be used to predict the jet behaviors of a well-mixing binary system.

关键词: mathematical     two-dimensional     flotsam-on-jetsam     fluidization velocity     physical    

Key issues in development of offshore natural gas hydrate

Shouwei ZHOU, Qingping LI, Xin LV, Qiang FU, Junlong ZHU

《能源前沿(英文)》 2020年 第14卷 第3期   页码 433-442 doi: 10.1007/s11708-020-0684-1

摘要: As a new clean energy resource in the 21st century, natural gas hydrate is considered as one of the most promising strategic resources in the future. This paper, based on the research progress in exploitation of natural gas hydrate (NGH) in China and the world, systematically reviewed and discussed the key issues in development of natural gas hydrate. From an exploitation point of view, it is recommended that the concepts of diagenetic hydrate and non-diagenetic hydrate be introduced. The main factors to be considered are whether diagenesis, stability of rock skeleton structure, particle size and cementation mode, thus NGHs are divided into 6 levels and used unused exploitation methods according to different types. The study of the description and quantitative characterization of abundance in hydrate enrichment zone, and looking for gas hydrate dessert areas with commercial exploitation value should be enhanced. The concept of dynamic permeability and characterization of the permeability of NGH by time-varying equations should be established. The ‘Three-gas co-production’ (natural gas hydrate, shallow gas, and conventional gas) may be an effective way to achieve early commercial exploitation. Although great progress has been made in the exploitation of natural gas hydrate, there still exist enormous challenges in basic theory research, production methods, and equipment and operation modes. Only through hard and persistent exploration and innovation can natural gas hydrate be truly commercially developed on a large scale and contribute to sustainable energy supply.

关键词: natural gas hydrate exploitation offshore     diagenetic and non-diagenetic hydrate     solid-state fluidization method     dessert in enrichment area     three-gas combined production on gas hydrate abundance    

天然气水合物开采技术研究现状与展望

李清平,周守为,赵佳飞,宋永臣,朱军龙

《中国工程科学》 2022年 第24卷 第3期   页码 214-224 doi: 10.15302/J-SSCAE-2022.03.022

摘要:

天然气水合物是一种世界公认的最具潜力的清洁能源,目前我国对水合物的勘探开采研究正进入关键突破阶段,南海泥质粉砂天然气水合物成藏机理与赋存规律尚不明晰,开采过程水合物分解相变机制与安全、高效技术仍需进一步探明。本文重点介绍了包括降压开采、固态流化开采等在内的天然气水合物开采技术的研究与应用现状,并通过分析天然气水合物开采技术存在的问题给出了相应的发展建议。研究建议,推动天然气水合物、深部油气等多气源立体开采基础研究和重大工程;强化技术融合,推进理论与实践协同并进;推进天然气水合物中试尺度实验和多场耦合的数值模拟大科学平台建设;建立健全天然气水合物的相关标准等措施,以提升我国天然气水合物开采技术的研发水平和技术成熟度,以期早日实现天然气水合物的大规模商业化开发,服务于我国的能源安全战略。

关键词: 天然气水合物;开采技术;降压;固态流化;联合方法    

第十六届国际流态化会议(Fluidization XVI)

会议日期: 2019年05月26日

会议地点: 中国/广西/桂林

主办单位: 美国化学工程师协会,中国颗粒学会

标题 作者 时间 类型 操作

Self-sustained catalytic combustion of CO enhanced by micro fluidized bed: stability operation, fluidization

期刊论文

Development of a hydrodynamic model and the corresponding virtual software for dual-loop circulating fluidized beds

Shanwei Hu, Xinhua Liu

期刊论文

Performance of inverse fluidized bed bioreactor in treating starch wastewater

M. RAJASIMMAN, C. KARTHIKEYAN

期刊论文

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-based CO2 capture sorbents

期刊论文

CFD simulation of jet behaviors in a binary gas-solid fluidized bed: comparisons with experiments

Pei PEI, Guiying WU, Bangting YU, Kai ZHANG, Jianchun JIANG, Dongsheng WEN,

期刊论文

Key issues in development of offshore natural gas hydrate

Shouwei ZHOU, Qingping LI, Xin LV, Qiang FU, Junlong ZHU

期刊论文

天然气水合物开采技术研究现状与展望

李清平,周守为,赵佳飞,宋永臣,朱军龙

期刊论文

第十六届国际流态化会议(Fluidization XVI)

2019年05月26日

会议信息

赵跃民:气固流态化干法分选 (2022年8月14日)

2022年09月05日

会议视频